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Organometallics for Sustainable Chemistry and Quantum Technologies
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© Grégory Nocton - Personal website - gregory.nocton.at.polytechnique.edu
M2 -
Supramolecuar chemistry and molecular self-assembly
Thermodynamics and kinetics for supramolecular chemistry
Papers studied:
An AAAA–DDDD quadruple hydrogen-bond array
Barry A. Blight, Christopher A. Hunter, David A. Leigh, Hamish McNab and Patrick I. T. Thomson
Nature Chemistry, 2011, 244
Determining association constants from titration experiments in supramolecular chemistry
Pall Thordarson
Chem. Soc. Rev.
, 2011,
40
, 1305
What is Cooperativity?
Christopher A. Hunter and Harry L. Anderson
Angew. Chem. Int. Ed.
, 2009,
48
, 7488
Examples of supramolecular objects
Paper studied
:
Supramolecular Modeling of Mono-copper Enzyme Active Sites with Calix[6]arene-based Funnel Complexes
Nicolas Le Poul, Yves Le Mest, Ivan Jabin, and Olivia Reinaud
Acc. Chem. Res.
, 2015,
48
, 2097
Mimicking the Protein Access Channel to a Metal Center: Effect of a Funnel Complex on Dissociative versus Associative Copper Redox Chemistry
Nicolas Le Poul, Benedicte Douziech, Joceline Zeitouny, Gregory Thiabaud, Helene Colas, Françoise Conan, Nathalie Cosquer, Ivan Jabin, Corinne Lagrost, Philippe Hapiot, Olivia Reinaud and Yves Le Mest
J. Am. Chem. Soc.
, 2009,
131
, 17800
Monocopper Center Embedded in a Biomimetic Cavity: From Supramolecular Control of Copper Coordination to Redox Regulation
Nicolas Le Poul, Morgan Campion, Bénédicte Douziech, Yannick Rondelez, Loïc Le Clainche, Olivia Reinaud and Yves Le Mest
J. Am. Chem. Soc.
, 2007,
129
, 8801
How Large Can We Build a Cyclic Assembly? Impact of Ring Size on Chelate Cooperativity in Noncovalent Macrocyclizations
Carlos Montoro-García, María J. Mayoral, Raquel Chamorro, and David Gonzμlez-Rodríguez
Angew. Chem. Int. Ed.
, 2017,
56
, asap
Examples of supramolecular objects II
Paper studied
:
A pH-Dependent, Mechanically Interlocked Switch: Organometallic [2]Rotaxane vs. Organic [3]Rotaxane
Philipp J. Altmann and Alexander Pçthig
Angew. Chem. Int. Ed.
, 2017,
56
, asap
Supramolecular Recognition Allows Remote, Site-Selective CH Oxidation of Methylenic Sites in Linear Amines
Giorgio Olivo, Giulio Farinelli, Alessia Barbieri, Osvaldo Lanzalunga, Stefano Di Stefano and Miquel Costas
Angew. Chem. Int. Ed.
, 2017,
56
, DOI: 10.1002/anie.201709280
Molecular Tweezers and Clips as Synthetic Receptors. Molecular Recognition and Dynamics in Receptor-Substrate Complexes
FRANK-GERRIT KLÄRNER AND BJÖRN KAHLERT
Acc. Chem. Res.
, 2003, 36, 219
Molecular Tectonics: From Simple Tectons to Complex Molecular Networks
MIR WAIS HOSSEINI
Acc. Chem. Res.
, 2005, 38, 31
3
Supramolecular chemistry in diagnosis and therapeutic chemistry