Sustainable Chemistry and Quantum Technologies


Group Agenda

ReDivaLan      RelaxMax     NiCatEther

LanAsCat     PhiBond

57. Molecular Lanthanide Switches for Magnetism and Photoluminescence

Münzfeld L., Dahlen M., Hauser A., Mahieu N., Moutet J., Tricoire M., Köppe R., La Droitte L., Cador O., Le Guennic B., Nocton G., Moreno-Pineda E.,* Ruben M.,* Roesky P. W.*
Angew. Chem. Int. Ed., 2023, accepted, DOI: 10.1002/anie.202218107

56. Structure and Bonding Patterns in Heterometallic Organometallics with linear Ln-Pd-Ln motifs 

Cemortan V., Simler T., Moutet J., Jaoul A., Clavaguéra C.,* Nocton G.*
Chem. Sci., 2023, DOI:10.26434/chemrxiv-2022-n4fbb

55. Back to the future of organolanthanide chemistry

Mahieu N., Piatkowski, J., Simler T.,* Nocton G.*
Chem. Sci., 2023, DOI: 10.1039/D2SC05976B

Highlighted as 2022 ChemSci Pick of the week collection
Highlighted in the 2022 Chemical Science HOT article collection

54. Electron Shuttle in N-heteroaromatic-Ni Catalysts for Alkene Isomerization

Tricoire, M., Wang. D., Rajeshkumar, T., Maron, L.,* Danoun G.*, Nocton G.*
JACS Au, 2022, 2, 1881-1888. DOI: 10.1021/jacsau.2c00251

53. CO Reductive Oligomerization by a Divalent Thulium Complex and CO2-Induced Functionalization

Simler T.,* McCabe K. M., Maron L., Nocton G.*
Chem. Sci. 2022, 13, 7449-7461. DOI: 10.1039/D2SC01798A

Highlighted as 2022 ChemSci Pick of the week collection and
Highlighted in the 2022 Chemical Science HOT article collection

Highlighted in Chemistryworld

52. Synthesis and Structure of Tris-cyclononatetraenyl Rare Earth Complexes [Ln(C9H9)3] (Ln = Y, Gd, Tb, Dy, Ho, Er, Tm)

Stetsiuk O., La Droitte, L., Goudy, V., Le Guennic, B., Cador O., Nocton G.*
Organometallics, 2022, 41, 133-140. DOI: 10.1021/acs.organomet.1c00590

51. Size controlled hapticity switching in [Ln(C9H9)(C8H8)] sandwiches

Tricoire M., Münzfeld L., Moutet, J., Mahieu N., La Droitte L., Moreno-Pineda E., Gendron F., Hilgar, J. D., Rinehart J. D. Ruben M., Le Guennic B., Cador O. Roesky P. W. * and Nocton G.*
Chem. Eur. J., 2021, 27, 13558-13567. DOI: 10.1002/chem.202101599
Cover, DOI: 10.1002/chem.202102617

50. Intermediate valence states in lanthanides compounds

Tricoire M., Mahieu N., Simler T.*, Nocton, G.*
Chem. Eur. J., 2021, 27, 6860. DOI: 10.1002/chem.202004735

49. Influence of a Lanthanide Ion on the Ni Site of a Heterobimetallic 3d-4f Mabiq Complex

Boyce S., Moutet J., Niederegger L., Simler T., Nocton G.* Hess C.*
Inorg. Chem., 2021, 60, 403. DOI: 10.1021/acs.inorgchem.0c03058

48. Bis-cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single Molecule Magnets

Moutet J., Schleinitz J., La Droitte L., Tricoire M., Gendron F., Simler T., Clavaguéra C., Le Guennic B., Cador O., Nocton, G.*
Angew. Chem. Int. Ed., 2021, 60, 6042. DOI: 10.1002/anie.202015428
Press CNRS

47. Redox activity of a dissymmetric ligand bridging divalent ytterbium and reactive nickel fragments

Wang D., Tricoire M., Moutet J., Nocton G.*
Inorg. Chem. Front., 2021, 8, 647. DOI: 10.1039/D0QI00952K

46. Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI2

Jaoul A., Yang Y., Casaretto N., Clavaguéra C.*, Maron L.*, Nocton G.*
Chem. Commun., 2020, 56, 11875-11878. DOI: 10.1039/D0CC05164K

45. Understanding the Multiconfigurational Ground – and Excited States in Lanthanide Tetrakis Bipyridine Complexes from Experimental and CASSCF Computational Studies

Halbach, R., Nocton G.,* Amaro-Estrada J., Maron L., Booth C., Andersen R. A.*
Inorg. Chem., 2019, 58, 12083-12098. DOI: 10.1021/acs.inorgchem.9b01393

44. Reversible Electrons Transfers in Organolanthanide Chemistry

Jaoul A., Tricoire M., Moutet J., Cordier M., Clavaguéra C.*, Nocton G.*
Chem. Squ., 2019, 3, 1. DOI: 10.28954/2019.csq.06.001

43. Reactive Heterobimetallic Complex Combining Divalent Ytterbium and Dimethyl Nickel Fragments

Wang D., Moutet J., Tricoire M., Cordier M., Nocton G.,*
Inorganics, 2019, 7, 58. DOI: 10.3390/inorganics7050058

42. Divalent Thulium Crown-ether Complexes with Field-Induced Slow Magnetic Relaxation

Xémard M., Cordier M., Molton F., Duboc C., Le Guennic B., Maury O., Cador O., and Nocton G.*
Inorg. Chem., 2019, 58, 2872-2880. DOI: 10.1021/acs.inorgchem.8b03551

41. Lanthanidocenes: Synthesis, Structure and Bonding of Linear Sandwich Complexes of Lanthanides

Xémard M., Zimmer S., Cordier M., Goudy V., Ricard L., Clavaguéra C., Nocton G.*
J. Am. Chem. Soc., 2018, 140, 14443-14449. DOI: 10.1021/jacs.8b09081
Press CNRS

40. A Copper Iodide Nanocluster

El Moll H., Cordier M., Nocton G., Massuyeau F., Latouche C., Martineau-Corcos C., Perruchas S*
Inorg. Chem., 2018, 57, 11761-11769. DOI: 10.1021/acs.inorgchem.8b03551

39. Phenylacetylene and Carbon Dioxide Activation by an Organometallic Samarium Complex

Goudy V., Xémard M., Karleskind S., Codier M., Alvarez Lamsfus C., Maron L, Nocton G.,*
Inorganics, 2018, 6, 82. DOI: 10.3390/inorganics6030082

38. Synthesis and Reactivity of Low-Valent f-Element Iodide Complexes with Neutral Iminophosphorane Ligands

Cheisson T., Ricard L., Heinemann F. W., Meyer K.,* Auffrant A.,* Nocton G.,*
Inorg. Chem., 2018, 57, 9230-9240. DOI: 10.1021/acs.inorgchem.8b01259

37. Small molecules activation with divalent samarium triflate: a synergistic effort to cleave O2

Xémard M, Cordier M., Louyriac E., Maron L., Clavaguéra* C., Nocton, G.*
Dalton Trans., 2018, 47, 9226-9229. DOI: 10.1039/C8DT02196A

36. Cerium Tetra(tropolonate) and Cerium Tetra(acethylacetonate) are Not Diamagnetic but Temperature-Independent Paramagnets

Halbach R. L., Nocton G.,* Booth C. H., Maron L., Andersen R. A.*
Inorg. Chem., 2018, 57, 7290-7298. DOI: 10.1021/acs.inorgchem.8b00928

35. Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes

Xémard M., Goudy V., Braun A., Tricoire M., Cordier M., Ricard L., Castro L., Louyriac E., Kefalidis C. E., Clavaguera C., Maron L., Nocton G.*
Organometallics, 2017, 36, 4660-4669.  DOI: 10.1021/acs.organomet.7b00630

34. Electronic structure of mono-oxidized copper and nickel phosphasalen complexes

Mustieles Marin I., Cheisson T., Chauhan R. S., Herrero C., Cordier M., Clavaguéra C.,* Nocton G.*, Auffrant A.*
Chem. Eur. J., 2017, 23, 17240-17255. DOI: 10.1002/chem.201703390

33. Tuning the stability of Pd(IV) intermediates using a redox non-innocent ligand combined with an organolanthanide fragment

Goudy V., Jaoul A., Cordier M., Clavaguéra C., Nocton G.*,
J. Am. Chem. Soc., 2017, 139, 10633-10636. DOI: 10.1021/jacs.7b05634

32. Assessment of density functionals for computing thermodynamic properties of lanthanide complexes

Jaoul A., Nocton G.*, Clavaguéra C.*
Chem. Phys. Chem., 2017, 18, 2688-2696. DOI: 10.1002/cphc.201700629

31. Effect of Cations on the Structure and Electrochemical Response of Polyoxometalate-Based Coordination Polymers

Salomon W., Paille G., Gomez-Mingot M., Mialane P., Marrot J., Nocton G., Mellot-Draznieks C., Fontecave M., Dolbecq A.*
Cryst. Growth Des., 2017, 17, 1600-1609. DOI: 10.1021/acs.cgd.6b01600

30. Divalent thulium triflate: a structural and spectroscopic study

Xémard M., Jaoul A., Cordier M., Molton F., Cador O., Le Guennic B., Duboc C., Maury O., Clavaguéra C., Nocton G.*
Angew. Chem. Int. Ed., 2017, 56, 4266-4271 (back cover). DOI: 10.1002/anie.201700576

29. Redox Initiated Reactivity of Dinuclear Niobium Imido Complexes

Kriegel B. M., Naested L. C. E., Nocton G., Lakshmi K. V., Lohrey T. D., Bergman R. G.*, Arnold J.*
Inorg. Chem., 2017, 56, 1626-1627. DOI: 10.1021/acs.inorgchem.6b02735

28. Synthesis and Characterization of 1,1’-diphosphaplumbocenes: oxidative ligand transfer with divalent thulium complexes

Jaroschik F., Momin A., Martinez A., Harakat D., Ricard L., Le Goff X.-F., Nocton, G.*
Organometallics, 2016, 35, 2032-2038. DOI: 10.1021/acs.organomet.6b00313

27. Tetramethylbiphosphinine Complexes of Cp*2Yb and Cp*2Sm: Solid-State Structure, Solution NMR Spectroscopy and Theoretical Calculations

Jaoul A., Clavaguéra C., Nocton G.*
New J. Chem., 2016, 8, 6643-6649. DOI: 10.1039/C6NJ00527F

26. η5 –η1 Iminophosphoranyl Pincer Ligands: Solid State Structures and Solution NMR 1JYb-P Coupling Constants

Cheisson T., Auffrant A., Nocton G.*
Organometallics, 2015, 34, 5470-5478. DOI: 10.1021/acs.organomet.5b00814

25. Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure and Ligand-Dependent Redox Behavior

Andrez J., Bozoklu, G., Nocton, G., Pécaut, J., Scopelliti R., Dubois, L., Mazzanti, M.*
Chem. Eur. J., 2015, 21, 15188-15200. DOI: 10.1002/chem.201502204

24. Geometry Flexibility of Copper Iodide Clusters: Variability in Luminescence Thermochromism

Benito Q., Le Goff X., Nocton G., Fargues A., Garcia A., Berhault A., Kahlal S., Saillard J. Y., Martineau C., Gacoin T., Boilot J.-P., Perruchas S.*
Inorg. Chem., 2015, 54, 4483-4494. DOI: 10.1021/acs.inorgchem.5b00321

23. Mechanochromic luminescence of Copper Iodide Clusters

Benito Q., Maurin I., Cheisson T., Nocton G., Fargues A., Garcia A., Martineau C., Gacoin T., Boilot J.-P., Perruchas S.*
Chem. A Eur. J., 2015, 21, 5892-5897. DOI: 10.1039/C9DT01161G

22. Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium

Nocton G.*, Ricard L.,
Chem. Commun., 2015, 51, 3578-3581. DOI: 10.1039/C5CC00289C

21. Electron Localization in a Mixed-valent Diniobium Benzene Complex

Gianetti T.L, Nocton G.*, Minasian S.G., Kaltsoyannis N., Kilcoyne A.L.D., Kozimor, S.A., Shuh, D.K., Tyliszczak, T., Bergman R.G.*, Arnold, J.*, 
Chem. Sci., 2015, 6, 993-1003. DOI: 10.1039/C4SC02705A

20. Carbon-Hydrogen Bond Breaking and Making in the Open-Shell Singlet Molecule, Cp*2Yb(4,7-Me2phen)

Nocton G.,* Booth C. H., Maron L., Ricard A., Andersen R. A.*
Organometallics, 2014, 33, 6819-6829. DOI: 10.1021/om500843z

19. Multiple One-electron Transfers in Bipyridine Complexes of Bisphospholyl Thulium

Jacquot L., Xémard M., Clavaguéra C., Nocton G.*
Organometallics, 2014, 33, 4100-4016. DOI: 10.1021/om500607r

18. Reversible Sigma C-C Bond Formation Between Phenanthroline Ligands Activated by (C5Me5)2Yb

Nocton G.*, Lukens W. W., Booth C. H., Rozenel S. S., Medling S. A., Maron L., Andersen R. A.*
J. Am. Chem. Soc., 2014, 136, 8626-8641. DOI: 10.1021/ja502271q

17. A Phosphasalen Nickel(III) Complex

Cao T-P-A., Nocton G., Ricard L., Le Goff X. F., Auffrant A.*
Angew. Chem. Int. Ed., 2014, 53, 1368-1372. DOI: 10.1002/anie.201309222

16. N-Aromatic heterocycles adducts of bulky [1,2,4-(Me3C)C5H2]2Sm: synthesis, structure and solution analysis

Nocton G.,* Ricard L.
Dalton Trans., 2014, 43 (11), 4380-4387. DOI: 10.1039/C3DT52641K

15. The influence of the Torsion Angle in 3,3’-Dimethyl,2,2’-bipyridine on the Intermediate Valence in (C5Me5)2Yb(3,3’-Me2-bipy)

Nocton G.,* Booth C. H., Maron L., Andersen R. A.*
Organometallics, 2013, 32, 5305-5312. DOI: 10.1021/om400528d

14. CO Activation by Diphosphine-Pt(0): Carbonate and Acetone Formation. Experimental and Mechanistic Study

Nicolas E., Nocton G.*, Mézailles N.*
Eur. J. Inorg. Chem., 2013, 22-23, 4000-4007. DOI: 10.1002/ejic.201300182

13. Diniobium Inverted Sandwich Complexes with µ-n6:n6-arene Ligands: Synthesis, Kinetic of Formation, and Electronic Structure

Gianetti T.L, Nocton G., Minasian S.G., Tomson N.C., Kilcoyne A.L.D., Kozimor S.A., Shuh D.K., Tyliszczak T., Bergman R.G.*, Arnold, J.*
J. Am. Chem. Soc. 2013, 135, 3224-3236. DOI: 10.1021/ja311966h

12. Thermal Dihydrogen Elimination from Cp*2Yb(4,5-Diazafluorene)

Nocton G., Booth C. H., Maron L., Andersen R. A.*
Organometallics, 2013, 32, 1150-1158. DOI: 10.1021/om300876b

11. Synthesis and X-Ray Structure of Ruthenium bis(acetylacetonate)(N,N,N',N'-tetramethylethylenediamine)

Halbach R. L, Nocton G., Andersen R. A.*
Dalton Trans. 2012, 41, 8809-8812. DOI: 10.1039/C2DT30810J

10. High energy resolution X-ray absorption spectroscopy study of uranium in varying valence states

Vitova T.*, Kvashnina K., Nocton G., Sukharina G., Denecke M. A., Butorin S. M., Mazzanti M., Cacciuffo R., Soldatov A., Behrends T., Geckeis H.
Phys. Rev. B, 2010, 82. DOI: 10.1103/PhysRevB.82.235118

9. Cation-cation Complexes of Pentavalent Uranyl: From Disproportionation Intermediates to Stable Clusters

Mougel V., Horeglad P., Nocton G., Pécaut J., Mazzanti M.*
Chem. Eur. J., 2010, 16, 48, 14365-14377. DOI: 10.1002/chem.201001929

8. Ligand Assisted Cleavage of Uranium Oxo-Clusters

Nocton G., Pécaut J., Filinchuk Y., Mazzanti M.*
Chem. Commun.  2010, 46, 2757-2759. DOI: 10.1039/B926580E

7. Synthesis, Structure and Bonding of Stable Complexes of Pentavalent Uranyl

Nocton G., Horeglad P.,Vetere V., Pécaut J., Dubois L., Maldivi P., Edelstein N.M., Mazzanti M.*
J. Am. Chem. Soc. 2010, 132, 495-508. DOI: 10.1021/ja9037164

6. Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed-Valent Uranyl Complex by Cation-Cation Interactions

Mougel V., Horeglad P., Nocton G., Pécaut J., Mazzanti M.*
Angew. Chem. Int. Ed. 2009, 48, 8477-8480. (Inside Cover). DOI: 10.1002/anie.200903457

5. Water Stability and Luminescence of Lanthanide Complexes of Tripodal Ligands Derived from 1,4,7-triazacyclononane: pyridine carboxamide versus picolinate donors

Nocton G., Nonat A., Gateau C. and Mazzanti M.*
Helvetica Chimica Acta 2009, 92, 2257 (invited issue). DOI: 10.1002/hlca.200900150

4. Pentavalent Uranyl Stabilized by a Dianionic Bulky Tetradentate Ligand

Horeglad P., Nocton G., Filinchuk Y., Pécaut J., Mazzanti M.*
Chem. Commun. 2009, 1843-1845. DOI : 10.1039/B821398D

3. Polynuclear Cation-Cation Complexes of Pentavalent Uranyl: Relating Stability and Magnetic Properties to Structure

Nocton G., Horeglad P., Pécaut J., Mazzanti M.*
J. Am. Chem. Soc. 2008, 130, 16633-16645. DOI: 10.1039/B821398D

2. A New Nitrido-Centred Uranium Azido Cluster obtained from a Uranium Azide

Nocton G., Pécaut J., Mazzanti M.*
Angew. Chem. Int. Ed. 2008, 47, 3040-3042 (Inside cover). DOI: 10.1002/anie.200705742

1. Self-Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low Valent Uranium

Nocton G., Burdet F., Pécaut J., Mazzanti M.*
Angew. Chem. Int. Ed. 2007, 43, 7584. DOI : 10.1002/anie.200702374